I don't have access to my books right now, but this link says 1942. Hawker Hurricane - Great Britain and this from wiki Hurricane IID http://en.wikipedia.org/wiki/Hawker_Hurricane_variants
From Mediterranean air war Vol 1 by Christopher F Shores "...it was in this area that the Hurricane IID tankbusters first put their 40 mm cannon armament into action on the 7th (June 1942)." Hope this helps.